Electronic and ionic dynamics coupled at solid-liquid electrolyte interfaces in porous composites of carbon black nanoparticles, poly(vinylidene fluoride) and gamma alumina

Abstract : Better fundamental understanding of the transport properties within nanocomposite materials consisting of interpenetrated percolating networks and used as electrodes is needed to improve their performance for a variety of devices. The simultaneous measurement of their effective ionic and electronic conductivities requires a sophisticated experimental set up. Here, the reciprocal influence of ionic and electronic transfers at different scales of model porous nanocomposites made of carbon black–poly(vinylidene fluoride)−γ alumina wetted by a nonaqueous electrolyte is investigated by broadband dielectric spectroscopy (BDS) from 40 to 1010 Hz, between 223 and 293 K. Experimental results show that the coupling of electronic and ionic dynamics at interfaces in the nanostructured composite material results in significant decrease of the electronic conductivity compared to the dry state and increase of the ionic conductivity compared to the bulk electrolyte.
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Journal of Physical Chemistry C, American Chemical Society, 2017, 121 (15), pp.8364-8377. 〈10.1021/acs.jpcc.6b12204〉
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https://hal-centralesupelec.archives-ouvertes.fr/hal-01659666
Contributeur : Olivier Dubrunfaut <>
Soumis le : vendredi 8 décembre 2017 - 16:30:25
Dernière modification le : jeudi 6 septembre 2018 - 16:08:03

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Eddie Panabiere, Jean-Claude Badot, Olivier Dubrunfaut, Aurélien Etiemble, Bernard Lestriez. Electronic and ionic dynamics coupled at solid-liquid electrolyte interfaces in porous composites of carbon black nanoparticles, poly(vinylidene fluoride) and gamma alumina. Journal of Physical Chemistry C, American Chemical Society, 2017, 121 (15), pp.8364-8377. 〈10.1021/acs.jpcc.6b12204〉. 〈hal-01659666〉

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