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Comparison of two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)]·H2O

Abstract : The two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands were compared. The structures of the complexes were analyzed using low-temperature data collected at 193.2 K. The two complexes were in the form of zigzag chains. The Co ion was five coordinate with a distorted trigonal-bipyramidal geometry in the first compound. The Cu ion in the second complex was in a distorted octahedral 4+2 environment.
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https://hal-centralesupelec.archives-ouvertes.fr/hal-02296838
Contributor : Amandine Lustrement <>
Submitted on : Wednesday, September 25, 2019 - 3:14:16 PM
Last modification on : Wednesday, July 1, 2020 - 4:22:03 PM

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L. Karanović, D. Poleti, J. Rogan, Goran Bogdanović, Anne Spasojevic - de Biré. Comparison of two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)]·H2O. Acta Crystallographica Section C Crystal Structure Communications, 2002, 58 (5), pp.m275-m279. ⟨10.1107/S0108270102004341⟩. ⟨hal-02296838⟩

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