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Journal articles
Chemical bonding in methylidyne complexes Neutron diffraction study on a single crystal of BrW3 (CH(dmpe-d)12)2 at 100 K and 293 K.
Abstract : Carbyne complexes have been extensively studied but only a few of them contain the M[triple bond, length as m-dash]C–H moiety (M = transition metal). In order to contribute to the debate about the linearity of this fragment, two neutron diffraction experiments on single crystal have been performed at 100 and 293 K on the trans-W(CH)(dmpe)2Br (dmpe = 1,2-bis(dimethylphosphino)ethane) (1). The results point, without ambiguity, to the linearity of the fragment. The specific behaviour of the dmpe ligand is modelled and interpreted.
Cited literature [42 references]
https://hal.archives-ouvertes.fr/hal-02296844
Contributor : Amandine Lustrement <>
Submitted on : Wednesday, September 30, 2020 - 3:12:05 PM
Last modification on : Sunday, January 10, 2021 - 10:37:00 PM
Long-term archiving on: : Monday, January 4, 2021 - 8:36:02 AM
Contributor : Amandine Lustrement <>
Submitted on : Wednesday, September 30, 2020 - 3:12:05 PM
Last modification on : Sunday, January 10, 2021 - 10:37:00 PM
Long-term archiving on: : Monday, January 4, 2021 - 8:36:02 AM
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hal-02296844. wcarb texte.pdf
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