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Journal articles
Direct Evidence of Lithium Ion Migration in Resistive Switching of Lithium Cobalt Oxide Nanobatteries
van Son Nguyen
1
van Huy Mai
2
Pascale Auban-Senzier
3
Claude Pasquier
3
Kang Wang
3
Marcelo J. Rozenberg
3
Nathalie Brun
3
Katia March
3
François Jomard
4
John Giapintzakis
5
Cristian Mihailescu
6
Evripides Kyriakides
7
Pavan Nukala
8
Thomas Maroutian
9
Guillaume Agnus
9
Philippe Lecoeur
9
Silvia Matzen
9
Pascal Aubert
9
Sylvain Franger
10
Raphaël Salot
11
Pierre-Antoine Albouy
3
David Alamarguy
1
Brahim Dkhil
8
Pascal Chrétien
1
Olivier Schneegans
1
van Son Nguyen 1
Author
van Huy Mai 2
Author
Pascale Auban-Senzier 3
Author
Claude R. Pasquier 3
Author
François Jomard 4
Author
John Giapintzakis 5
Author
Cristian Mihailescu 6
Author
Evripides Kyriakides 7
Author
Pavan Nukala 8
Author
Thomas Maroutian 9
Author IdHAL : tmaroutian ORCID : https://orcid.org/0000-0001-5535-391X
Guillaume Agnus 9
Author
Philippe Lecoeur 9
Author
Pierre-Antoine Albouy 3
Author
David Alamarguy 1
Author IdHAL : david-alamarguy
Brahim Dkhil 8
Author IdHAL : brahim-dkhil
Pascal Chrétien 1
Author IdHAL : pascal-chretien
Olivier Schneegans 1
Author IdHAL : olivier-schneegans ORCID : https://orcid.org/0000-0001-9741-3327
1
GeePs - Laboratoire Génie électrique et électronique de Paris (11, rue Joliot Curie
Plateau de Moulon
91192 Gif sur Yvette - France)
- UP11 - Université Paris-Sud - Paris 11 (Bâtiment 300 - 91405 Orsay cedex - France)
- UPMC - Université Pierre et Marie Curie - Paris 6 (4 place Jussieu - 75005 Paris - France)
- CentraleSupélec (3, rue Joliot Curie, Plateau de Moulon, 91192 GIF-SUR-YVETTE Cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR8507 (France)
2
Le Quy Don Technical University (Vietnam)
3
LPS - Laboratoire de Physique des Solides (Bat. 510 91405 Orsay cedex - France)
- UP11 - Université Paris-Sud - Paris 11 (Bâtiment 300 - 91405 Orsay cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR8502 (France)
4
GEMAC - Groupe d'Etude de la Matière Condensée (URF de Sciences
Bâtiment Fermat
45 avenue des Etats Unis
78035 Versailles - France)
- UVSQ - Université de Versailles Saint-Quentin-en-Yvelines : UMR8635 (55 avenue de Paris - 78035 Versailles cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR8635 (France)
5
University of Cyprus [Nicosia] (University House "Anastasios G. Leventis" P.O. Box 20537, 1678 Nicosia - Cyprus)
7
University of Cyprus, Cyprus (University of Cyprus, Nicosia, Cyprus - Cyprus)
- University of Cyprus, Cyprus (France)
8
SPMS - Laboratoire Structures, Propriétés et Modélisation des solides (CentraleSupélec - Bâtiment Eiffel - 3 rue Joliot-Curie - 91190 GIF-SUR-YVETTE - France)
- CentraleSupélec (3, rue Joliot Curie, Plateau de Moulon, 91192 GIF-SUR-YVETTE Cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR8580 (France)
9
C2N - Centre de Nanosciences et de Nanotechnologies [Orsay] (Batiment 220 Université Paris Sud - France)
- UP11 - Université Paris-Sud - Paris 11 : UMR 9001 (Bâtiment 300 - 91405 Orsay cedex - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CNRS - Centre National de la Recherche Scientifique : UMR 9001 (France)
10
ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay (bat. 420 91405 ORSAY CEDEX - France)
- UP11 - Université Paris-Sud - Paris 11 (Bâtiment 300 - 91405 Orsay cedex - France)
- CNRS - Centre National de la Recherche Scientifique : UMR8182 (France)
11
DACLE-LETI - Département d'Architectures, Conception et Logiciels Embarqués-LETI (CEA Grenoble - France)
- CEA-LETI - Commissariat à l'énergie atomique et aux énergies alternatives - Laboratoire d'Electronique et de Technologie de l'Information : DRT/LETI (MINATEC 17, rue des Martyrs, 38054, Grenoble Cedex 9 - France)
- DRT (CEA) - Direction de Recherche Technologique (CEA) : DRT (France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRT (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- DRT (CEA) - Direction de Recherche Technologique (CEA) : DRT (France)
- UGA [2016-2019] - Université Grenoble Alpes [2016-2019] (CS 40700 - 38058 Grenoble cedex - France)
Abstract : Lithium cobalt oxide nanobatteries offer exciting prospects in the field of nonvolatile memories and neuromorphic circuits. However, the precise underlying resistive switching (RS) mechanism remains a matter of debate in two‐terminal cells. Herein, intriguing results, obtained by secondary ion mass spectroscopy (SIMS) 3D imaging, clearly demonstrate that the RS mechanism corresponds to lithium migration toward the outside of the Li$_x$CoO$_2$ layer. These observations are very well correlated with the observed insulator‐to‐metal transition of the oxide. Besides, smaller device area experimentally yields much faster switching kinetics, which is qualitatively well accounted for by a simple numerical simulation. Write/erase endurance is also highly improved with downscaling – much further than the present cycling life of usual lithium‐ion batteries. Hence very attractive possibilities can be envisaged for this class of materials in nanoelectronics.
Document type :
Journal articles
Complete list of metadata
https://hal-centralesupelec.archives-ouvertes.fr/hal-01799107
Contributor : Olivier Schneegans <>
Submitted on : Thursday, May 24, 2018 - 1:14:34 PM
Last modification on : Saturday, April 10, 2021 - 3:33:05 AM
Contributor : Olivier Schneegans <>
Submitted on : Thursday, May 24, 2018 - 1:14:34 PM
Last modification on : Saturday, April 10, 2021 - 3:33:05 AM
Identifiers
- HAL Id : hal-01799107, version 1
- DOI : 10.1002/smll.201801038
Collections
CENTRALESUPELEC | CNRS | UVSQ | CEA | CEA-UPSAY | DRT | GEMAC | INC-CNRS | LETI | SPMS | PHEMADIC | SPMS-AXE2 | SORBONNE-UNIVERSITE | GEEPS | CEA-GRE | SU-SCIENCES | UP-SCIENCES | UGA | GS-ENGINEERING | GS-CHIMIE
Citation
van Son Nguyen, van Huy Mai, Pascale Auban-Senzier, Claude Pasquier, Kang Wang, et al.. Direct Evidence of Lithium Ion Migration in Resistive Switching of Lithium Cobalt Oxide Nanobatteries. Small, Wiley-VCH Verlag, In press, ⟨10.1002/smll.201801038⟩. ⟨hal-01799107⟩
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